![]() ![]() At the same PMMA content, the blends crystallized from ethanol had a higher degree of crystallinity ( X c) of PVDF compared with those from DMF. ![]() For the blends crystallized from DMF, their peak melting temperatures and lamellar thickness calculated by WAXD showed a first increasing and then decreasing tendency. Thermal properties of in situ blends were also dominated by crystallization solvent and PMMA content. The addition of PMMA could reduce the spherulite size of PVDF. The in situ blends crystallized from DMF and ethanol presented spherulites morphology and numerous minute particle structures, respectively. The crystallization morphology was related to crystallization solvent and PMMA content. However, the relative fraction of β phase of PVDF in blends crystallized from ethanol varied with PMMA content. For the in situ PVDF/PMMA blends, β phase of PVDF was predominant when they were crystallized from their good solvent DMF, while PVDF exhibited well-defined α and β phases from non-solvent ethanol. ![]() The crystalline phases of PVDF were dependent on crystalline solvents and independent on PMMA content. The PVDF/PMMA blends were obtained by in situ polymerization of methyl methacrylate (MMA) in the solution of PVDF in DMF. The crystallization behavior of poly(vinylidene fluoride)/poly(methyl methacrylate) (PVDF/PMMA) blends was investigated at different PMMA content and from two solvents N, N-dimethylformamide (DMF) and ethanol. ![]()
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